An ultrafast microscope makes movies one femtosecond at a time
New CU Boulder research harnesses the power of an ultrafast microscope to study molecular movement in space and time.
The interactions in photovoltaic materials that convert light into electricity happens in femtoseconds. How fast is that? One femtosecond is a quadrillionth of a second. To put that in perspective, the difference between a second and a femtosecond is comparable to the difference between the second right now and 32 million years ago.
Subatomic particles like electrons move within atoms, and atoms move within molecules, in femtoseconds. This speed has long presented challenges for researchers working to make more efficient, cost-effective and sustainable photovoltaic materials, including solar cells. Imaging materials on the nanoscale with high enough spatial resolution to uncover the fundamental physical processes poses an additional challenge.
Understanding how, where and when electrons move, and how their movement depends on the molecular structure of these materials, is key to honing them or developing better ones.
Ultrafast nano-imaging of structure and dynamics in a perovskite quantum material also used for photovoltaic applications. Different femtosecond laser pulses are used to excite and measure the material. They are focused to the nanoscale with an ultrasharp metallic tip. The photo-excited electrons and coupled changes of the lattice structure (so called polarons, red ellipses) are diagnosed spectroscopically with simultaneous ultrahigh spatial and temporal resolution. (Illustration: Branden Esses)
Building on more than five years of research developing a unique ultrafast microscope that can make real-time “movies” of electron and molecular motion in materials, a team of University of Colorado Boulder scientists published in Science Advances the results of significant innovations in ultrafast nanoimaging, visualizing matter at its elementary atomic and molecular level.
The research team, led by Markus Raschke, professor of physics and JILA fellow, applied the ultrafast nanoimaging techniques they developed to novel perovskite materials. Perovskites are a family of organic-inorganic hybrid materials that are efficient at converting light to electricity, generally stable and relatively easy to make…